1/1/2024 0 Comments Pyruvate anomeric carbon![]() ![]() The size of the cyclic hemiacetal ring adopted by a given sugar is not constant, but may vary with substituents and other structural features.Īldohexoses usually form pyranose rings and their pentose homologs tend to prefer the furanose form, but there are many counter examples. For most five- and six-carbon sugars, the cyclic forms predominate in equilibrium since they are more stable. Sugars are often shown in their open-chain form, however, in aqueous solution, glucose, fructose, and other sugars of five or six carbons rapidly interconvert between straight-chain and cyclic forms. Unlike most of the biochemical reactions you will see in this text, sugar cyclization reactions are not catalyzed by enzymes: they occur spontaneously and reversibly in aqueous solution. Cyclic structures of this kind are termed furanose (five-membered) or pyranose (six-membered), reflecting the ring size relationship to the common heterocyclic compounds furan and pyran shown below.įuran (5-membered ring) and pyran (6-membered ring) structures Five and six-membered rings are favored over other ring sizes because of their low angle and eclipsing strain. Molecules which have both an alcohol and a carbonyl can undergo an intramolecular version of the same reaction forming a cyclic hemiacetal.īecause sugars often contain alcohol and carbonyl functional groups, intramolecular hemiacetal formation is common in carbohydrate chemistry. In Section 19-10 it was discussed that the reaction of one equivalent of an alcohol, in the presence of an acid catalyst, adds reversibly to aldehydes and ketones to form a hydroxy ether called a hemiacetal (R 2COHOR') (h emi, Greek, half). ![]()
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![]() ![]() We were a bit disappointed that the Florida exhibits were mostly closed, but our timing was just unfortunate. The animals seemed well cared for and content, and any interactions I saw with zoo staff reinforced the attachments between the staff and their charges. We were impressed by how clean the grounds were kept – people were always making sure any little bits of trash were picked up quickly. We have been watching the television series “The Zoo” and “Secrets of the Zoo” so when we planned a vacation to Florida we wanted to see the Tampa Zoo for ourselves. Not a good value for the $40.00 admission, wish I could say so. The grounds themselves all natural habitats for the animals, if there were some to put in them.but very impressive with the boardwalks, rock formations and waterfalls throughout the park. I will note on the positive, the aquarium was explicit-it was indoor and NOT closed so why were other indoor or walk-thru areas? There was a marine biologist student available to answer questions about the medical holding tanks, which are remarkable for the care of marine animals that become injured. There was only 1 bear, 2 tigers (they say the 2nd one was inside) no lions, 2 elephants, 1 giraffe, no apes nor chimps, only small hardly visible monkeys, 1 panther, 2 alligators (in FLORIDA? should have been crawling with them!) Lower the admission price since a lot of exhibits were closed due to COVID however, didn't understand why these exhibits were closed anyway mask wearing and being outdoors I did not bring any children, but $27.00 for a child to enter is also ridiculous. Allow an open "avoid the line" concept to purchase online tickets for the day of (I was on the website at 12:19 only to learn the cutoff was 12:00 to purchase a $3.00 savings. I would highly recommend spending a day here if you are in the area and enjoy animals.Īt the $39.95 price of admission, per individual, I would think more actual animals could be acquired. The only bad thing was that the tram was broken down the afternoon we were there. Besides, the money goes to support the animals. Yes, the food is a little pricey, but not really that bad. We spent most of the day there from maybe 10 until 4PM. Most of the animals were out and about, but some of the big cats and the bear were sleeping. The stingrays were cool even though we didnt feed them. We arrived as they were feeding them and got a great show. There were a number of keepers/handlers around and they were happy to answer questions. The displays were informative and there were few if any unlabeled enclosures. The animal enclosures were clean and the animals looked healthy. The zoo is pretty well laid out and the maps were pretty good. Masks were required in close contact areas. We went on a Tuesday and it really wasn’t very crowded. OK, I don’t know where the people leaving negative reviews went, but it probably wasn’t the same zoo I visited. The Florida panther, the African painted dog, okapi are all animals I had never seen before. I also saw some animals I had never seen before, and that was enjoyable. one ran into the fence ( it's very strong) and you could really see the power of these animals. When the baby rhino was attacked by one of the larger rhinos all hell broke loose and there was lots of running around, chasing. Two of them had stand off going on, staring each other down and literally drawing a line in the sand. The best part of our day was watching the rhinos. The manatees were wonderful and I expect some of the high cost is going to help care for animals that the zoo is rehabilitating. Great if you live local but not if you are visiting from another state. The upside is once you purchase the ticket you can come back all year as many times as you want. We found a place to get a burger in the children's zoo area and it was $10 a burger or $7 for a hot dog. A lot of areas weren't open for snacks or food. It was a cool day and there were not a lot of people at the zoo. I understand we are in the area of high priced attractions but this is more than twice the price of the zoo in our state. I thought the price of this zoo for the day was high at $40 a person. ![]() 1/1/2024 0 Comments Sip and shop hudson yards![]() ![]() ![]() ![]() News & World Report 2023 & 2022 Best Hotels Award Silver Medalist, Gay Travel 2022 & 2021 Award for Best Boutique Hotel, Safe Spaces LGBTQIA+ Certification 2023, Boutique Design’s 2019 Gold Key Award for Best Guest Room and Best Midscale Hotel, Surface Magazine’s 2019 Travel Award for Best Micro-Hotel, NYCxDesign’s 2019 Award for Best Bar/Lounge (Bar Feroce), and Travel Weekly’s 2019 Magellan Award for Best Midscale Hotel. Moxy Chelsea has been honored with Condé Nast Traveler’s 2022, 2021 & 2020 Readers’ Choice Awards: The Top 25 Hotels in New York City, U.S. 2 The Shops at Hudson Yards: New York’s super mall at Hudson Yards is the new retail mecca in Midtown Manhattan with 7 levels of high-end shops and restaurants (Hudson Yards, Subway 7 ). Our bar selection is curated to help you get those creative juices flowing, and our food menu caters to those who strive to have a brush in one hand and a fork. Sip and Shop Boutique is proud to bring you the latest styles in fashion for women and men. Moxy Chelsea marks the second collaboration between Yabu Pushelberg and Rockwell Group, the designers behind Moxy Times Square. Topping off the hotel is The Fleur Room, a glass-enclosed rooftop lounge with panoramic, 360° views. Look 100 stories down from the thrilling glass floor, lean out over the city on angled glass walls and sip champagne in the sky. The second floor Lobby Bar features Italian bites and cocktails. The month also brings an exclusive Sip & Shop event, as well. Guests enter through the overgrown Starbright Floral Design Residency, which doubles as the hotel’s entrance alongside the Café d’Avignon Pop-up. Its the start of Shine Bright, the dazzling light display that takes over The Shops & Restaurants. The platform-in-the-clouds will open on Mayoull be able to sip cocktails or get a light bite at the 100th-floor bar or dine at Peak, the 101st. Check out our store Sip & Shop, A Local Collection at San Tan. 10,212 likes 23 talking about this 2,136 were here. The building’s architecture honors the neighborhood with its industrial facade and soaring, greenhouse-style atrium. Hudson Yard Wine and Spirits 486 9th Avenue, New York, NY 10018 21 Get Delivery 2,210 products N/A average delivery 9 store rating WINE LIQUOR EXTRAS Best-selling wine View All Best Seller 4.8 (7,460) La Marca Prosecco Sparkling Wine 16.85 750.0ml bottle Best Seller 4. Sip & Shop - A Local Collection and Vintage & Vino Market, Gilbert, Arizona. Cozy bedrooms, designed with intelligence-and a touch of wit-are flooded with light thanks to floor-to-ceiling, wall-to-wall windows. 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We recommend using the native iOS or Android whenever possible, but if you prefer using the mobile browser (no download required), use this LINK. One of the most luxurious hotels in the city houses a stunningly elegant indoor pool. Search for "scavify" in the App Store or Google Play. We’ve made it easy to keep track through the Scavify app! NEW THIS SPRING! Attending the Sip and Shop? Want to win a $200 Gift Card to a Downtown Rutland business of your choosing? Visit all participating businesses during the event for your chance to win! This is a 21+ event and each attendee must bring a photo ID to show proof of age. Grab something quick on your way to work or sit and sip something from our single source collection. Don’t miss out on this unique event that introduces new tastes and treasures in Downtown Rutland. Downtown merchants will host vendors offering samples of Vermont products at the next Sip + Shop on Thursday, May 11th from 5-8 pm! Download the NEW Sip and Shop Passport app, pick up a map and tasting glass at the historic Paramount Theatre and visit all the participating locations at your leisure. ![]() ![]() ![]() This makes stop motion a more viable option to a “wider audience” due to the DSLR’s “affordability and performance”. ![]() And with support for the Blackmagic Production Camera 4K, Dragonframe widens its user base even more, with 4K support being a big draw for many shooters these days. Dragonframe helps during shooting through a variety of video assist tools, such as “step-to-live, onionskinning, auto-toggling, and drawing (virtual grease pencil)”.ĭragonframe 3.6 is available now, free for Dragonframe 3 owners and available at $295 for new users. There is also a fully functional trial version available for download.įor more on Dragonframe and its new 3.6 update, see the press release below. Be sure to also visit Dragonframe 3.6 Stop Motion Adds Support for Canon EOS 7D Mark II and Nikon D3300ĭZED Systems LLC develops Dragonframe stop motion animation software–used by top studios for feature films, music videos, commercials, and broadcast television series. The powerful software simplifies stop motion animation with integrated USB control of Canon and Nikon DSLRs. New in this release is support for the following cameras: Dragonframe 3.6 adds support for popular DSLRs and digital film cameras. The Nikon D3200 and D3300 are the first entry-level Nikon DSLRs supported by Dragonframe. Their affordability and performance with the software open up the possibility of creating professional-looking stop motion animation to a wider audience. The Blackmagic Design Production Camera 4K is a digital film camera that captures beautiful images at 4K resolution. ![]() With the new support in Dragonframe 3.6, it is a great choice for combining 4K live action with stop motion animation.ĭragonframe is the premier frame-grabbing software for stop motion animation and time-lapse photography. ![]() ![]() ![]() ![]() When you're not playing pool, head downstairs for live music and dancing. In addition to billiard tables, Skylark features a 22-foot tournament size shuffleboard court, two dartboards and a Rock-Ola Peacock jukebox, along with a lot of vintage artwork and photographs, including a museum-quality poster collection. There are three Brunswick Anniversary billiard tables and two smaller bar tables available for play, though be aware that leagues play at Skylark Lounge on Thursdays. Head up to Skylark's Pair O' Dice Poolroom, which Billiards Digest voted one of the nation's top three new poolrooms when it opened in 2006. Skylark has been serving Denver customers since 1943, and it keeps on evolving. Recommended for Billiards because: Sobo 151 is proof that pool goes just as well with Czech bites and brews as it does with British and American eats and drinks.Ĭhristine's expert tip: Love karaoke? Join the karaoke fun at Sobo 151 on Thursdays, Saturdays and pub staples including chili, hamburgers and wings. What goes with Czech beer? European faves such as potato pancakes, schnitzel, chicken paprika and beef goulash, and the kitchen also serves up traditional U.S. Happy hour runs weekdays 3 to 6 p.m., plus Wednesdays from 10 p.m. The time difference isn't an issue: Sobo 151 opens at 7 a.m. The bar televises the UEFA games–European football, that is, especially Czech matches. You can catch an Avalanche game for sure, but soccer is front and center. and 75 cents a game after, or to challenge themselves at Pac-Man, trivia and karaoke. Patrons come to play pool on three tables, which are free with a purchase until 6 p.m. This Czech-owned sports bar has a European vibe and generous selection of Czech beers. Read more about Punch Bowl Social Denver → for Monday Game Night, the pool table is free and bowling is just $5 per hour including shoes. Recommended for Billiards because: Punch Bowl Social is all about good times and good games, including pool.Ĭhristine's expert tip: Starting at 9 p.m. Note: Take a look at the "punch bowl graveyard" above the bar, where all the vintage punch bowls go to die–or at least to be displayed. There's plenty to love on the menu every other day and night, too. If you want to bring the kids in to play some of your fave old-school games, do it on the weekend when Punch Bowl Social opens at 8 a.m. Did we mention the private karaoke room? The cost for pool is $10 per hour, except during Monday Game Night. 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We still offer this option today, and it is as popular as ever! Here are some benefits of our $1 bars: Since 1949, people have come to rely on our $1 bar as their primary way to fundraise. Pictured is the 2022 One Dollar Box CHOCOLATE BAR FUNDRAISING ![]() 12/31/2023 0 Comments Class manager dance studio pro![]() ![]() ![]() Questions & Answers: here, try to answer the most important questions about studio rules, restrictions, group membership, teaching outfits, etc.The schedule should be short and clear (you can create a schedule using Google.doc, and add just a link to your dance studio website ).Trial lesson: create a convenient application form with a couple of fields (name, phone number, and a “Sign up” button is the best choice).Prices: combine your subscriptions into blocks, specify clear prices, conditions, and expiration dates.This makes the reviews look more realistic. Testimonials: just a positive text review is not enough! 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Thermal envelopes, gel ice packs and expedited shipping are measures meant to increase the likelihood that your order will arrive intact and unmelted however, due to the multiple variables in shipping we do not provide a guarantee that any products using any service or packaging will arrive unmelted.In most cases and especially during warm weather months the ice packs will last at most two days and will not last past 3 days when packed with thermal envelopes. Neither the ice packs nor thermal envelopes are designed to last the 4-5 days that standard shipping may take to arrive. It is highly recommended that you purchase an expedited shipping option in addition to thermal packaging to increase the likelihood that your order will arrive unmelted.For a more detailed explanation of what options are available please see our Warm Weather FAQ page. Ice packed shipping options are available April 15th through October 15th.In most cases a 4-5 day standard shipping option will be used for the 48 contiguous states however, in a few cases a longer shipping method might be used for larger or heavier orders and orders going to Alaska or Hawaii. The most economical shipping option will be used when the free shipping option is chosen.International, APO/FPO/DPO, and US territory orders are not eligible for free shipping and all shipping costs will be calculated at checkout.Free shipping is available to the 50 US states only.The $49.00 threshold must be reached before taxes and after any additional discounts.Any single order over $49.00 qualifies.Please see information below on Thursday, Friday, and weekend shipments.All orders placed after 5:00pm CST will be counted as being placed the following business day.In most cases with most carriers w eekends and federal holidays are not considered business days. The transit times do not include the 1-2 business days handling time allowing for us to pick, pack and ship your order. The transit time quoted at checkout with your chosen shipping service is the number of business days that your product will be in transit with the shipping carrier after your item has been shipped.Weekends and federal holidays are not considered business days. All orders have a handling time of 1-2 business days regardless of what shipping service is chosen.If you purchase UPS 2nd day, Overnight, or Next Day service along with ice packs and thermal envelopes and your order still arrives melted please contact us and we will work with you on a resolution.įor more details please see our shipping policies page.Ice packs and thermal envelopes are meant to be an additional tool to help your order "beat the odds" but is not guaranteed. ![]()
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